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Synthetic MoS2 crystals have been I2 （iodine） intercalated to achieve p-type doping.
High purtiy WS2 crystals have been I2 （iodine） intercalated to achieve p-type doping.
Natural MoS2 is an indirect gap semiconductor （1.2 eV） but becomes highly luminescent in the monolayer from at 1.9 eV （quasi-particle / optical band gap）.
Tungsten disulfide （2H-WS2） crystals are extremely rare in nature and are less than 10 microns in the quartz / MoS₂ matrix.
Zirconium disulfide （ZrS₂） is an indirect gap layered semiconductor in the bulk and becomes direct gap semiconductor in monolayer form.
Zirconium disulfide （ZrS₂） is an indirect gap layered semiconductor in the bulk and becomes direct gap semiconductor in monolayer form.
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