钙钛矿材料 ITIC （n-type acceptor）

简要描述：ITIC represents the start of a new generation of electron-accepting small molecules for organic photovoltaic （OPV） applications.

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更新时间：2024-06-03
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价格

Batch	Quantity	Price
M1002	100 mg	6245.40
M1002	250 mg	10885.29
M1002	500 mg	18302.70
M1002	1g	30825.60

General Information

Purity	≥99.0% (1H NMR)
Full name	3,9-bis(2-methylene-(3-(1,1-dicyanomethylene)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2’,3’-d’]-s-indace,2-b:5,6-b’]dithiophene
Synonyms	ITIC
CAS number	1664293-06-4
Chemical formula	C94H82N4O2S4
Molecular weight	1427.94
HOMO/LUMO	HOMO = -5.48 eV, LUMO = -3.83 eV [1]
Classification/Family	Non-fullerene acceptors (NFAs), Organic semiconducting materials, Low band gap small molecule, Small molecular acceptors (SMAs), Organic Photovoltaics, Polymer solar cells, NF-PSCs.

Chemical structure of ITIC; CAS No. 664293-06-4; Chemical formula: C94H82N4O2S4.

Applications

ITIC represents the start of a new generation of electron-accepting small molecules for organic photovoltaic (OPV) applications. The energy levels of ITIC allow for good alignment with low band-gap polymers, resulting in enhanced charge separation efficiency and reduced energy loss. ITIC also has strong and broad absorption characteristics, from visible to near infrared and peaking at 700 nm, giving it the potential to increase the total absorption of an OPV device.

These properties have enabled ITIC to be the first small molecule to outperform fullerenes as the electron acceptor in an OPV device. When used in conjunction with PBDB-T (PCE12), a power conversion efficiency (PCE) of over 11% was achieved, compared to less than 8% when PC70BM was used as the electron acceptor. Additionally, ITIC proved to have excellent thermal stability, with devices showing no losses after being held at 100 °C for 250 hours [1].

Characterisation (1H NMR)

1H NMR spectrum of ITIC in CDCl3

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钙钛矿材料 ITIC （n-type acceptor）

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